含氮杂环多核茂铁类燃速催化剂的设计与合成  

Design and Synthesis of Combustion Catalysts Bearing Nitrogenous Heterocyclic Polynuclear Ferrocenyl Derivatives

作　　者：高勇[1] 李恒东[1] 柯成锋[1] 谢莉莉[1] 袁耀锋[1] 

机构地区：[1]福州大学化学化工学院,福建福州350108

出　　处：《化学推进剂与高分子材料》2010年第1期34-37,共4页Chemical Propellants & Polymeric Materials

基　　金：福建省自然科学基金(2009J05028和2006J0112);教育部留学回国人员科研启动基金资助项目

摘　　要：设计合成了含氮杂环多核茂铁类燃速催化剂,通过1H-NMR、FT-IR和质谱对目标产物进行表征。用循环伏安法对目标产物的电化学性质进行研究,探讨其多组分氧化还原的电化学行为与结构的关系。利用差热分析(DTA)和热重(TG)研究了在高氯酸铵(AP)中分别添加质量分数5%目标产物2c后的热分解性能,发现目标产物2c有一定的燃速催化性能。The combustion catalysts bearing nitrogenous heterocyclic polynuclear ferrocenyl derivatives were designed and synthesized. The structures of the target compounds were characterized by 1H-NMR, FT-IR and mass spectrum. The electrochemical properties of the target compounds were investigated by the cyclic voltammetry. The relationship between multi- component redox electrochemical behavior and structure was discussed. The thermal decomposition characteristics of AP with 5% （mass fraction） target compound 2c were investigated by the differential thermal analysis （DTA） and thermogravimetry （TG）. The results show that the title compound 2c has certain combustion catalytic characteristics.

关 键 词：二茂铁衍生物 燃速催化剂 含氮杂环化合物 电化学行为 

分 类 号：O643.36[理学—物理化学]