Geochemical Signatures of Early Paleogene Source Rocks in the Sanshui Basin, South China  

作　　者：LIU Chunlian Franz T. FURSICH CHEN Ling CHE Xiaoguang WU Jie 

机构地区：[1]Department of Earth Sciences, Sun Yat-Sen University, Guangzhou 510275, China [2]GeoZentrum Nordbayern der Universitgit Erlangen Erlangen D-91054, Germany

出　　处：《Acta Geologica Sinica(English Edition)》2010年第1期145-154,共10页地质学报（英文版）

基　　金：the Natural Science Foundation of China (No. 40872024, 40272011);the Natural Science Foundation of Guangdong Province (No. 04009757), respectively

摘　　要：The Honggang member of the early Paleogene Buxin Formation is the main source rock in the Sanshui Basin, characterized by organic-rich black shales with the cyclic recurrence of organic- poor sediments. The geochemical characteristics of the Honggang member have been documented to determine the organic matter types and depositional environments in this paper. The organic matter of the black shales mainly consists of a mixture of land plant-derived and phytoplankton-derived organic matter. Total organic carbon content （TOC）-sulfur-iron （Fe） relationships suggest that the organicrich black shales were deposited under dysoxic-to-euxinic water conditions. The time that iron minerals remained in contact with H2S in anoxic waters possibly influenced the formation of syngenetic pyrite, and organic carbon controlled the formation of diagenetic pyrite. Organic-poor intervals usually show pyrite sulfur enrichment and higher degree of pyritization values relative to low organic carbon contents. This resulted from HS- diffusing downward from overlying organic-rich sediments and formed Fe sulfides through reactions with sufficient Fe. Trace elements generally exhibit low concentrations and little TOC dependence, suggesting some degree of depletion in these elements in the early Paleogene sediments of the Sanshui Basin. This probably resulted from cyclic recurrences of oxic benthic conditions, which promoted the remobilization of trace elements and caused the low concentration of trace elements.The Honggang member of the early Paleogene Buxin Formation is the main source rock in the Sanshui Basin, characterized by organic-rich black shales with the cyclic recurrence of organic- poor sediments. The geochemical characteristics of the Honggang member have been documented to determine the organic matter types and depositional environments in this paper. The organic matter of the black shales mainly consists of a mixture of land plant-derived and phytoplankton-derived organic matter. Total organic carbon content （TOC）-sulfur-iron （Fe） relationships suggest that the organicrich black shales were deposited under dysoxic-to-euxinic water conditions. The time that iron minerals remained in contact with H2S in anoxic waters possibly influenced the formation of syngenetic pyrite, and organic carbon controlled the formation of diagenetic pyrite. Organic-poor intervals usually show pyrite sulfur enrichment and higher degree of pyritization values relative to low organic carbon contents. This resulted from HS- diffusing downward from overlying organic-rich sediments and formed Fe sulfides through reactions with sufficient Fe. Trace elements generally exhibit low concentrations and little TOC dependence, suggesting some degree of depletion in these elements in the early Paleogene sediments of the Sanshui Basin. This probably resulted from cyclic recurrences of oxic benthic conditions, which promoted the remobilization of trace elements and caused the low concentration of trace elements.

关 键 词：organic matter type carbon-sulfur-iron relationship trace element black shale SanshuiBasin 

分 类 号：P618.51[天文地球—矿床学] P618.13[天文地球—地质学]