十六胍亚硫酸盐的制备研究  

Study on the Preparation of Hexadecylguanidium sulfite

作　　者：陈田田[1,2] 王锦堂[1] 韦长梅[2,3] 

机构地区：[1]南京工业大学理学院应用化学系,江苏南京210009 [2]淮阴师范学院化学化工学院,江苏淮安223300 [3]江苏省低维材料化学重点建设实验室,江苏淮安223300

出　　处：《淮阴师范学院学报（自然科学版）》2009年第4期318-321,共4页Journal of Huaiyin Teachers College;Natural Science Edition

基　　金：江苏省教育厅自然科学基金项目(05KJD150039);江苏省化学重点建设实验室基金项目(JSKC09060)

摘　　要：研究了以十六胺和三氧化硫脲为原料制备十六胍亚硫酸盐的方法.通过考察反应时间、温度和物料比等因素对产物收率影响的实验,获得了优化反应条件为:以95%乙醇为溶剂,7.85g十六胺和3.10g三氧化硫脲于50℃反应2 h,产品收率可达75.91%.目标产品通过了红外、质谱和核磁共振碳谱表征.The preparation methods of hexadecylguanidium sulfite from hexadecylamine and aminoiminomethanesulfonic acid was studied.The infections of reaction temperature,time and molar ratio on the reaction yield were researched.The optimum synthesis conditions for title compound were obtained as follows： 7.85g hexadecylamine and 3.10g aminoiminomethanesulfonic acid reactied for 2 h at 50℃ in the solvent of ethanol with the yield of 75.91%.The target compound was characterized by IR,MSand 13C-NMR.

关 键 词：十六胺 三氧化硫脲 十六胍亚硫酸盐 

分 类 号：TQ225.26[化学工程—有机化工]