荧光剂二(2-二苯氧化膦基)二苯醚配合铕的合成及发光研究  

Study of the Synthesis and Fluorescent Properties of Eu-complexed Bis(2-(diphenylphosphino)phenyl)ether Oxide

作　　者：张文官[1] 秦练[1] 赵生敏[1] 

机构地区：[1]北京印刷学院印刷包装材料与技术北京市重点实验室,北京102600

出　　处：《包装工程》2010年第3期5-9,共5页Packaging Engineering

基　　金：北京市教委科技面上项目(KM201010015);北京印刷学院印刷包装材料与技术北京市重点实验室开放课题(KF200811)

摘　　要：由二苯醚制得二(2-二苯膦基)二苯醚,再经双氧水氧化得到二(2-二苯氧化膦基)二苯醚(DPEPO),然后DPEPO和2-噻吩基三氟甲基丙二酮(TTA)与铕离子配位合成Eu(TTA)3DPEPO。测试结果表明其在THF和固体薄膜中613和616nm处有很强的荧光发射。测定其熔点245℃,分解温度为343℃。与Eu(TTA)3(TPPO)2进行比较,证明中性双齿DPEPO的刚性结构增强了铕配合物的荧光性能和热稳定性,可满足于印刷包装防伪等的需要。Bis（2-（diphenylphosphino）phenyl）ether prepared by diphenyl ether was oxidized by H2O2to obtain bis（2-（diphenylphosphino）phenyl）ether oxide （DPEPO）. Eu（TTA）3DPEPO was synthesized by Eu3＋coordinating with DPEPO and TTA （TTA=2-thenoyltri fluoroacetone）. The test result showed that the strong emission peaks of the complex appeared at 613nm in diluted THF and 616 nm in solid film respectively; the melting point of Eu（TTA）3DPEPO is at 245 ℃ and its thermal decomposition temperature （Td） appears at 343 ℃. In addition,compared with Eu（TTA）3（TPPO）2,Eu（TTA）3DPEPO has excellent fluorescent properties and a high thermal stability originating from the rigidity influence of DPEPO as bidentate ligand. It was concluded that Eu（TTA）3DPEPO is desirable to be used in anti-counterfeiting printing and packaging.

关 键 词：二苯醚 二(2-二苯氧化膦基)二苯醚 铕配合物 荧光 热稳定 

分 类 号：TB484.3[一般工业技术—包装工程]