Pt(111)表面上表层Fe(FeO)结构和次表层Fe结构的可控转变(英文)  

Controlled Transformation of the Structures of Surface Fe(FeO) and Subsurface Fe on Pt(111)

作　　者：马腾[1] 傅强[1] 崔义[1] 张镇[1] 王珍[1] 谭大力[1] 包信和[1] 

机构地区：[1]中国科学院大连化学物理研究所催化基础国家重点实验室,辽宁大连116023

出　　处：《催化学报》2010年第1期24-32,共9页

基　　金：Supported by the National Natural Science Foundation of China(20603037,20733008,and20873143);the National Basic Research Program of China(973 Program,2007CB815205);Hundred Talents Program of Chinese Academy of Sciences

摘　　要：利用扫描隧道显微镜(STM)和X射线光电子能谱(XPS)对Pt(111)表面制备的Fe单层薄膜及其在不同环境气氛条件下的多种结构进行了研究.在温度为487K的Pt(111)表面制备出了完整的Fe单层薄膜Fe/Pt(111).对Fe/Pt(111)依次升高温度进行超高真空退火,STM和XPS结果表明退火温度高于800K时,表面Fe原子扩散到次表层区域,形成次表层Fe结构Pt/Fe/Pt(111).Pt/Fe/Pt(111)在O2氧化气氛中经850K退火可转变成表面FeO薄膜FeO/Pt(111).FeO/Pt(111)结构在温和的H2还原气氛中(600K)转变成表面Fe结构,进一步的还原处理(800K)则可以重新生成Pt/Fe/Pt(111).控制样品的环境气氛在O2和H2之间切换,使得表面Fe(FeO)和次表面Fe可以重复地转变.本研究实现了多种Fe-Pt表面结构的可控制备,可为合理地设计高效、价廉的催化剂提供借鉴.Monolayer Fe films on Pt（111） and their derived structures under different environments were investigated by scanning tunneling microscopy （STM） and X-ray photoelectron spectroscopy （XPS）. The growth of monolayer Fe films was seen at 487 K. The surface compo- sition and structure of the Fe/Pt（111） surface were monitored by XPS and STM during stepwise annealing under vacuum. Surface Fe was driven into the subsurface region during annealing above 800 K. This resulted in a Pt-skin surface of Pt/Fe/Pt（111）. Oxidation of the Pt-skin structure in O2 produced a FeO surface structure, FeO/Pt（111）. This was transformed into a surface Fe structure by mild reduction in H2 （600 K） and into subsurface Fe by further severe reduction （800 K）. The transformation of surface Fe （FeO） and subsurface Fe in Pt（111） was reversible in cycled oxidation and reduction treatments. The results demonstrated the controlled preparation of various Fe-Pt surfaces. This can be important for the design of high-performance and low-cost catalysts.

关 键 词：双金属催化剂 氧化物 Pt富集表面 反相模型体系 

分 类 号：O614.826[理学—无机化学]