超支化有机硅树脂的制备、改性及其应用  

Preparation,modification and application of hyperbranched organosilicon resins

作　　者：王晶[1] 周继亮[1] 火文君[1] 张爱清[1] 张道洪[1,2] 

机构地区：[1]中南民族大学催化材料科学国家民委-教育部共建重点实验室,武汉430074 [2]苏州海博特树脂科技有限公司,苏州215214

出　　处：《化工新型材料》2010年第1期14-16,40,共4页New Chemical Materials

基　　金：中国博士后科学基金面上项目(20070420773);武汉市青年科技晨光计划(200850731406)

摘　　要：综述了以ABn(n=2,3,4)型单体制备超支化聚碳硅烷、超支化聚碳硅氧烷和超支化聚烷氧基硅烷三类超支化有机硅树脂的合成工艺及其改性技术,重点介绍了制备含不饱和双键和环氧基团的功能性超支化有机硅树脂单体的分子设计与制备技术。论述了超支化有机硅树脂在薄膜材料、复合催化剂、增强助剂等领域的应用研究进展。Synthesis and modification technology of hyperbranched organosilicon resins from ABn（n= 2,3,4） monomers were summarized in detail, including hyperbranched polycarbosilanes, hyperbranehed polycarbosiloxanes and hyper- branched polyalkoxysilanes. Especially, monomer molecular designation and preparation method of funcational hyper- branched organosilicon resins containing unsaturated double-bonds and epoxy group also were discuused. Application pro- gress of hyperbranched organosilicon resins in membrane materials, complex catalysts and reinforcement additives fields were reviewed.

关 键 词：超支化聚合物 超支化有机硅树脂 制备 

分 类 号：TQ324.21[化学工程—合成树脂塑料工业] TQ325.14