聚磷酸铵阻燃剂制备工艺研究  

Study on Preparation of Ammonium Polyphosphate Fire Retardants

作　　者：崔益顺[1] 

机构地区：[1]四川理工学院材料与化学工程学院,四川自贡643000

出　　处：《四川理工学院学报（自然科学版）》2010年第1期69-70,73,共3页Journal of Sichuan University of Science & Engineering(Natural Science Edition)

基　　金：自贡市科技局重点项目(08X01)

摘　　要：以磷酸二氢氨和尿素为原料,采用磷酸铵热缩合法制备聚磷酸铵阻燃剂。对反应温度、聚合时间和原料摩尔配比进行单因素实验,结果表明:反应温度在300℃-320℃,反应时间为150m in,反应物(磷酸二氢氨∶尿素)摩尔比为1∶1时,产品的阻燃性能最好,聚合度较大。Ammonium polyphosphate fire retardants is prepared with ammonium dihydrogen phosphate and urea, the way that is ammonium thermal legitimate. The effects of preparation conditions, such as reaction temperature, polymerization time, components proportion is studied with the single-factor test. The results showed that reaction temperature 300℃-320℃, polymerization time 150 min, and molar rate of monoammonium phosphate and urea 1： 1, the products is best performance of fire-retardant and the dgree polymerization is greater.

关 键 词：聚磷酸铵 阻燃性 工艺条件 

分 类 号：TQ126.35[化学工程—无机化工]