(S)-腺苷蛋氨酸分子印迹毛细管电色谱整体柱制备与评价  

Preparation and Evaluation of Molecularly Imprinted Monolith for (S)-Adenosylmethionine in Capillary Electrochromatography

作　　者：李燕丽[1] 刘雁红[1] 邓启良[1] 

机构地区：[1]天津科技大学理学院,天津300457

出　　处：《天津科技大学学报》2010年第1期24-27,共4页Journal of Tianjin University of Science & Technology

基　　金：国家自然科学基金资助项目(20605024);天津科技大学自然科学基金资助项目(20040103)

摘　　要：以(S)–腺苷蛋氨酸为模板分子,采用热引发一步法制备具有手性识别能力的分子印迹毛细管整体柱.在电色谱模式下,考察该色谱柱的识别性能.结果表明:制备的分子印迹整体柱在电色谱模式下具有良好的手性识别能力.Molecularly imprinted monolith based on （S）-adenosylmethionine was developed by in situ thermal initiation polymerization in capillary. The resulted monolith was further evaluated in capillary electrochromatography. The results indicated that the monolith showed well chiral recognition ability.

关 键 词：毛细管电色谱 整体柱 分子印迹 腺苷蛋氨酸 

分 类 号：O658[理学—分析化学]