氢转移反应的研究概述  

Research progress in hydrogen transfer reaction

作　　者：龚灵[1] 周少东[1] 陈新志[1] 

机构地区：[1]浙江大学化工系,浙江杭州310027

出　　处：《化工进展》2010年第3期478-483,489,共7页Chemical Industry and Engineering Progress

基　　金：国家自然科学基金(20776127);国家科技支撑计划课题(2007BAI34B07);浙江省自然科学基金(Y4090045;R4090358)资助项目

摘　　要：氢转移反应是利用氢供体作为氢源对氢受体进行还原的一类反应,该反应与普通的氢气加氢反应相比,反应条件温和、对设备要求不高,在实验室研究和工业生产中均有广阔的应用前景。本文作者在研究氢转移反应还原芳磺酸的基础上,对氢转移反应的工艺条件、催化剂和氢供体种类、适用的反应类型等进行了较系统的总结,重点对近年来的相关文献进行了综述,表明氢转移反应是一种高效、绿色、资源化利用氢供体的氢化、氢解还原工艺。Hydrogen transfer reaction is a kind of reduction reaction,in which the hydrogen donor is used as hydrogen source.Compared with hydrogenation using hydrogen gas,hydrogen transfer reaction is widely applicable both in laboratory research and industrial production,benefit from its mild reaction condition and low equipment requirement.Based on the hydrogen transfer reaction of aromatic sulfonic acid,related reaction factors are summarized,including reaction condition,catalyst,hydrogen donor and applicable reaction types.Related literatures published after the year of 2000 are mainly reviewed.Hydrogen transfer reaction is indicated to be an efficient and green technology to perform hydrogenation and hydrogenolysis reduction.

关 键 词：氢转移反应 反应条件 催化剂 氢供体 反应类型 

分 类 号：O63[理学—高分子化学]