含哒嗪酮的二糖基碳二亚胺的合成  

Synthesis of Diglycosyl Carbodiimmides Containing Pyridazinone

作　　者：陶晶[1] 谷新华[2] 

机构地区：[1]伊犁师范学院生命与资源环境系,新疆奎屯833200 [2]独山子石化公司乙烯厂聚丙烯车间,新疆克拉玛依833600

出　　处：《河南师范大学学报（自然科学版）》2010年第1期170-172,共3页Journal of Henan Normal University(Natural Science Edition)

基　　金：伊犁师范学院科研基金(2008YB031)

摘　　要：2,3,6,2′,3′,4′,6′-七-O-乙酰基-糖基异硫氰酸酯分别与1,4,5,6-四氢-6-哒嗪酮-3-甲酰肼1和1,6-二氢-6-哒嗪酮-3-甲酰肼2反应,制得4种硫脲,再将硫脲用氧化汞在CHCl3/H2O作用下脱硫化氢,制得新化合物糖基哒嗪酮碳二亚胺1c-1d和2c-2d.化合物的结构经1H NMR,IR,元素分析得以证实.The reaction of 2,3,6,2＇,3＇,4＇,6＇-hepta-O-acetyl-glucosyl isothiocyanate with 1,4,5,6-tetrahydro-6-pyridazinone-3-carboxylic acid hydrazides 1 and 1,6-dihydro-6-pyridazinone-3-Carboxylic acid hydrazides 2 furnishes four thioureas. Then these thioureas are desulfurated and transformed into the corresponding glucosyl carbodiimides 1c-1d and 2c-2d using HgO in CHCl3/H2O at room temperature. The structures of all compounds have been established by 1H NMR,IR and elemental analysis.

关 键 词：硫脲 糖基异硫氰酸酯 碳二亚胺 

分 类 号：O621[理学—有机化学]