N-氧化吡啶-2-甲醛衍生物的配合物研究(Ⅰ)——与二胺生成的双Schiff碱铜配合物的合成和晶体结构  

Studies on Coordination Compounds with Picolinaldehyde N-Oxide Derivatives as Ligands (Ⅰ)——syntheses and Crystal Structures of Cupric Complexes with Bis-Schiff Bases from Picolinaldehyde N-Oxide and Diamines

作　　者：臧焰[1] 陆勤[1] 尹湛峰 曾成[1] 戴安邦[1] 周忠远[2] 

机构地区：[1]南京大学配位化学研究所 [2]中国科学院成都分析测试中心

出　　处：《高等学校化学学报》1989年第1期1-5,共5页Chemical Journal of Chinese Universities

基　　金：中国科学院科学基金

摘　　要：报道了N-氧化吡啶-2-甲醛(Pio)与乙二胺(en)及1,3-丙二胺(tn)生成的双Schiff碱Cu(Ⅱ)配合物([Cu(Pioen)H_2O](ClO_4)_2和[Cu(Piotn)(H_2O)_2](ClO_4)2)的合成和晶体结构。晶体[Cu(Pioen)H_2O_3(ClO_4)_2属正交晶系,空间群P2_12_12_2,α=7.9534(19),b=7.6768(48),c=26.1037(189),Z=4,R=0.077 1,R_w=0.0771。晶体[Cu(Piotn)-(H_2O)_2](ClO_4)_2属正交晶系,空间群P^(nam),α=7.1360(24)。b=13.7887(42),0=22.2556(81),Z=4,R=0.0491,R_w=0.0491。结构由Patterson函数及Fourier合成法解出,经全矩阵最小二乘法修正至收敛。Cupric complexes of bis-Schiff bases prepared by condensation of pico-linaldehyde N-Oxide(pio) with ethylene diamine(en) and trimethylene diamine(tn) , [Cu(Pioen)H2O](ClO4)2 and CCu(Piotn) (H2O) 2](ClO4)2, were synthesised and their crystal structures were determined. The main crystallographic data are as follows. CCu(Pioen)H2CO(ClO4) 2, ortborhombic system, space group P212121, a = 7.953 4 (19) A, b = 9.676 8(48) A, c = 26.1 03 7 (1 89) A , Z = 4 , R = 0. 077 1; CCu(Piotn) (H2O) 2](ClO4) 2, ortborhombic system, space group -Pnaw,a = 7.1360 (24)A, 6 = 13.788 7(42) A.c = 22.255 6(81) A,Z = 4, R = 0.049 1. The intensity data were collected on R 3m/E four-circle diffractometer with Mo Ka radiation. The structures were solved by Patterson method and refined by full matrix least-square method.

关 键 词：配合物 吡啶衍生物 晶体结构 

分 类 号：O623.511[理学—有机化学]