3-羟基-1-金刚烷甲酸钴邻菲咯啉配合物的合成和晶体结构  

Synthesis and Crystal Structure of Cobalt Complex with 3-Hydroxy-1-adamantanecarboxylic Acid

作　　者：胡晓春[1] 刘建风[1] 边玉燕[1] 赵国良[1] 

机构地区：[1]浙江师范大学化学与生命科学学院,浙江金华321004

出　　处：《化学研究》2010年第2期22-25,共4页Chemical Research

基　　金：浙江省科技计划资助项目(2006C31028)

摘　　要：以硫酸钴、邻菲咯啉(phen)和3-羟基-1-金刚烷甲酸(HOC10H14COOH)为原料,合成了配合物[Co(HOC10H14COO)2(H2O)(phen)].H2O;利用元素分析、红外光谱、热重分析对产物进行了表征,采用单晶X射线衍射方法测定了其晶体结构.结果表明,所合成的配合物C34H42N2O8Co属于单斜晶系,空间群C2/c,a=2.69798(7)nm,b=1.14319(3)nm,c=2.29092(6)nm,β=120.498(1)°,V=6.0883(3)nm3,Z=8,Mr=665.63,F(000)=2808,Dc=1.452g.cm-3,μ(Mo-Kα)=0.765mm-1;R1=0.0805,wR2=0.2209.其通过氢键和π-π堆积作用相结合,形成稳定的二维超分子结构.A novel cobalt complex, [Co（HOG10H14COO）2（H2O）（phen）]·H2O was synthe sized from COSO4 · 7H2 O, phen and 3-hydroxy-l-adamantanecarboxylic acid （HOC10H14 COOH）. It was characterized by means of elemental analysis, infrared spectrometry, and ther- mogravimetric analysis. At the same time, its crystal structure was determined by making use of single crystal X-ray diffraction technique. Results show that the synthetic complex, C34 H42 N2 O8Co, crystallizes in the monoclinic system and belongs to space group C2/c,a=2.69798（7）nm,b=1.14319（3）nm,c=2.29092（6）nm,β=120.498（1）°,V665.63,F（000）=2808,Dc=1.452g·cm^-3,μ（Mo-Kα）=0.765mm^-1;R1=0.0805,wR2=0.2209, It exists in stable two dimensional supermolecular structure through hydrogen bonds and π-π interaction.

关 键 词：3-羟基-1金刚烷甲酸 钴配合物 合成 晶体结构 

分 类 号：O624.42[理学—有机化学]