景德镇与德化青花瓷原料来源的质子诱发X射线荧光分析  

Proton Induced X-ray Emission Analysis of Sources of Raw for Blue-and-White Porcelain From Jingdezhen and Dehua Area

作　　者：刘舜民[1] 杨大伟[2] 李融武[3] 李国霞[4] 承焕生[5] 郑炯鑫 陈丽芳 

机构地区：[1]南阳理工学院教育学院,河南南阳483000 [2]河南广播电视大学,河南郑州450008 [3]北京师范大学物理系,北京100875 [4]郑州大学物理工程学院,河南郑州450052 [5]复旦大学现代物理研究所,上海200433 [6]德化陶瓷博物馆,福建德化362500

出　　处：《原子能科学技术》2010年第2期252-256,共5页Atomic Energy Science and Technology

基　　金：国家自然科学基金资助项目(50772101);河南省自然科学基金资助项目(0611011500)

摘　　要：为了解景德镇和德化地区不同时期青花瓷的原料来源、成分和分类关系,用质子激发X射线荧光分析技术,分别无损测定34个样品胎、透明釉、青花釉中的主量化学组成,将所有样品的测量数据进行模糊聚类分析。结果表明:多数德化地区青花瓷胎样品和景德镇地区青花瓷胎样品的原料来源和分类关系明显不同;8个明代景德镇地区的青花瓷透明釉样品和多数德化地区青花瓷透明釉样品的原料来源和配方明显不同;除个别样品外,两地区多数青花釉样品分为截然不同的两大类,这为无损鉴别两地区青花瓷提供了一条重要的技术途径。In order to find out sources of raw, ingredients and classification relationship for Blue-and-White porcelain from Jingdezhen and Dehua area in different time, 34 Blue- and-White porcelain samples were selected. The chemical ingredients of every sample were determined by proton induced X-ray emission. The chemical ingredients data of all samples were further analyzed using fuzzy cluster analysis. The results indicate that the sources of raw and classification relationship of majority bodies from Blue-and-White porcelain of Dehua and Jingdezhen area are commendably differentiated. The sources of raw and batch formulas of eight transparent, enamel samples from Jingdezhen area in Ming Dynasty and majority transparent enamel samples from Dehua area are commend- ably differentiated. Except one or two samples, majority Blue-and-White glaze samples from two areas are obviously different, and it might be an important path for non- destructive discrimination among Blue-and-White porcelains from two areas.

关 键 词：景德镇青花瓷 德化青花瓷 质子激发X射线荧光分析 主量化学组成 原料来源 模糊聚类分析 

分 类 号：TQ17[化学工程—硅酸盐工业] K87[历史地理—考古学及博物馆学]