载邻菲罗林配体的三维有序大孔聚苯乙烯材料的制备及表征  

Preparation and Characterization of Three-Dimensionally Ordered Macroporous Polystyrene Functionalized with 1,10-Phenanthroline

作　　者：杨惠芳[1,2] 王燕燕[1] 刘宾元[1] 张旭[1] 刘盘阁[1] 闫卫东[1] 

机构地区：[1]河北工业大学高分子科学与工程研究所,天津300130 [2]石家庄铁道学院材料学院,河北石家庄050043

出　　处：《高分子材料科学与工程》2010年第3期123-126,共4页Polymer Materials Science & Engineering

基　　金：国家自然科学基金面上项目(50273009);河北省自然科学基金(E2007000052);教育部功能高分子材料重点实验室开放基金(2006-007);河北省教育厅科研计划项目(2007307)

摘　　要：采用胶体晶模板法合成了结构规整的三维有序聚合物材料,并在孔壁上引入了氯甲基。以氯甲基化的孔材料为基础进一步将含双齿N的邻菲罗林配体引到孔壁上,实现了聚合物孔材料的功能化,并通过扫描电镜(SEM),红外光谱(FT-IR)及热失重对各步所得产物进行表征。结果表明,成功将邻菲罗林配体负载到孔内,功能化后的孔材料很好地保持了三维有序大孔材料的结构特征,且孔材料在200℃左右呈现较好的耐热性。Three-dimensionally ordered macroporous polystyrenes were prepared via SiO2 template approach.The pores were functionalized by chloromethylation,then the bidentate ligand（1,10-phenanthrolin）was anchored by means of functional group transformation.The ordered macroporous materials were characterized by scanning electron microscope（SEM）,infrared spectroscopic（IR）,and thermogravimetry analysis（TG）.The results reveal that the pores are successfully bonded with 1,10-phenanthroline and the original morphology of ordered macroporous materials is remained after functionalization.The heat resistance and mechanical properties of the porous materials are good under temperature up to 200 ℃.

关 键 词：三维有序大孔材料 聚苯乙烯 氯甲基化 邻菲罗林 功能化 

分 类 号：TQ325.2[化学工程—合成树脂塑料工业]