1-(2-羧基苯基甲酰基)氨基硫脲及其Cu^+配合物的NMR研究  

NMR STUDIES ON 1 (2 CARBOXYBENZOYL) THIOSEMICARBAZIDE AND ITS COPPER(I) COMPLEX

作　　者：吴达旭[1] 沈旭[1] 

机构地区：[1]中国科学院福建物质结构研究所

出　　处：《波谱学杂志》1998年第6期547-556,共10页Chinese Journal of Magnetic Resonance

摘　　要：利用１Ｈ１ＨＣＯＳＹ，１Ｈ１３ＣＨＭＱＣ，ＨＭＢＣ等２ＤＮＭＲ技术对一种新的配体１（２羧基苯基甲酰基）氨基硫脲（Ｈ３Ｌ）进行１Ｈ、１３ＣＮＭＲ谱数据分析与归属，对于它与Ｃｕ＋离子配位的化合物［Ｃｕ２（Ｈ３Ｌ）２Ｃｌ２］（Ｈ２Ｏ）３也作了１Ｈ、１３ＣＮＭＲ的测定，简单讨论了它的配位行为，粗略确定了它的结构．In this paper 1H- 1H COSY, 1H- 13 C HMQC and HMBC 2D NMR techniques were used to analyze and assign the 1H and 13 C NMR spectra of a newly synthesized compound 1 (2 carboxybenzoyl) thiosemicarbazide(H 3L), The 1H、 13 C NMR spectra of its copper (I) complex Cu 2(H 3L) 2Cl 2 (H 2O) 3 have also been measured. Its coordination property is briefly discussed, and the structure of the complex is suggested.

关 键 词：氨基硫脲 铜(I)配合物 核磁共振波谱 

分 类 号：O614.121[理学—无机化学]