对苯基双乙内酰硫脲衍生物的合成与表征  

Synthesis and characterization of p-phenyl-bis-thiohydantoins derivatives

作　　者：吕全建[1,2] 南黎[1] 李建平[1] 王宗仁[1] 

机构地区：[1]河南师范大学化学与环境科学学院河南省环境污染监测重点实验室,河南新乡453007 [2]郑州牧业工程高等专科学校质量检测与管理系,河南郑州450011

出　　处：《化学试剂》2010年第2期114-116,共3页Chemical Reagents

基　　金：河南省自然科学基金资助项目(0611021700);河南省教育厅自然科学基金资助项目(2007150024)

摘　　要：以对苯二甲醛为原料,制得对苯基双异硫氰酸酯,再和L构型的氨基酸反应制得11种含有双杂环基团的对苯基双乙内酰硫脲类衍生物,其中有9种未见文献报道。产物经1HNMR、13CNMR和元素分析得到了确认和表征。Eleven p-phenyl-bis-thiohydantoins derivatives containing two heterocyelic structures were synthesized from L-amino acid and p-phenylene diisothiocyanate, which was obtained from p-phenyl-dimethanal. Among these products nine of them have not been reported previously. The title compounds reported were characterized by means of IHNMR,1SCNMR and elemental analysis.

关 键 词：对苯二甲醛 对苯基双异硫氰酸酯 对苯基双乙内酰硫脲 

分 类 号：O626.2[理学—有机化学]