多功能咔咯配合物的合成与应用进展  

Progress in synthesis and application of multifunctional corrole complexes

作　　者：朱卫华[1] 赵晓锋[1] 王晓红[1] 吴元钊[1] 欧忠平[1] 

机构地区：[1]江苏大学化学化工学院应用化学系,江苏镇江212013

出　　处：《化学试剂》2010年第2期117-122,176,共7页Chemical Reagents

基　　金：江苏省自然科学基金资助项目(BK2008226);江苏省国际科技合作项目基金资助项目(BZ2007058;GJ2007006)

摘　　要：咔咯(Corrole)是由4个吡咯共轭相连而形成的新型卟啉类大环配合物,它们能稳定结合具有较高氧化态的金属离子,所形成的金属配合物具有比较独特的光化学、电化学、光物理和光生物性质。研究表明,咔咯是一类非常重要的多功能配合物,它们在精细化学品领域具有广阔的应用前景。对咔咯配合物的主要合成方法、配合物用作精细化工催化剂、燃料电池电极催化材料、抗肿瘤光敏剂、电化学传感器和非线性光学材料等方面的研究和应用作了综述。Corroles are novel porphyrin-like macrocyclic complexes with four connected pyrroles in the molecule.Corroles can stabilize metal ions with higher oxidation states,leading to the formation of metallocorroles which have unique photochemical,electrochemical,photophysical and photobiological properties.The research results indicate that corroles are very important multifunctional complexes with wide applications in the area of fine chemicals.The main methods for synthesis of corroles,and the recent progress in research and application of the complexes as catalysts in fine chemical industry,electrode catalytic materials in fuel cell,anti-tumor photosensitizer,electrochemical sensors and non-linear materials were reviewed.

关 键 词：咔咯 多功能配合物 精细化学品 合成 应用 

分 类 号：O626[理学—有机化学]