同步冷却技术在微波辅助有机合成中的应用  

Application of microwave irradiation with simultaneous cooling in organic synthesis

作　　者：蔡高[1] 穆小静[1] 夏之宁[1] 

机构地区：[1]重庆大学化学化工学院,重庆400030

出　　处：《化学试剂》2010年第2期129-133,共5页Chemical Reagents

基　　金：科技部国际合作项目(2006DFA43520);国家自然科学基金资助项目(20775096;20805060)

摘　　要：同步冷却技术作为微波化学领域的一项新技术,可以使某些有机反应速度加快,产率提高,选择性变好,因此同步冷却条件下的微波辅助有机合成成为研究的热点之一。从具有同步冷却的微波反应装置、同步冷却条件下微波辅助有机合成的反应特点、同步冷却技术在低温微波化学中的应用和该技术在研究"微波的非热效应"中的应用4个方面进行综述,总结并展望了它在微波化学中的发展前景。Simultaneous cooling technique as an effective technique in microwave chemistry can improve the synthetic efficiency in some reactions of organic synthesis.The organic reaction with simultaneous cooling technique features a quicker reaction rate,higher yields,and better selectivity compared to the microwave chemistry.The reaction instruments,the reaction characteristics,the low temperature microwave-assisted reactions and the application of non-thermal microwave effects were summarized in this article,and the prospects of this technique were also referred to.

关 键 词：微波辐射 同步冷却 有机合成 综述 

分 类 号：O621.25[理学—有机化学]