激光串级溅射团簇反应装置简介  

Laser Double Ablation Cluster Reactor

作　　者：刘鹏[1] 郑卫军[1] 高振[1] 朱起鹤[1] 

机构地区：[1]中国科学院化学研究所分子反应动力学国家重点实验室

出　　处：《Chinese Journal of Chemical Physics》1998年第4期303-306,共4页化学物理学报（英文）

摘　　要：报道了一种研究团簇反应的新装置──激光串级溅射反应装置，论述了该装置的结构和工作原理，利用这一装置研究了银与硫团簇的反应。实验表明，银和硫团簇的反应得到了［ＡｇＳ４］＋［ＡｇＳ］＋、［ＡｇＳ１２］＋和［ＡｇＳ１６］＋的反应产物。与用付立叶变换离子回旋共振谱仪（ＦＴＩＣＲ）得到的银和硫团簇的反应结果相比，证明了用该装置研究团簇反应的有效性。This paper reported a new apparatus, called laser double ablation reactor,for study on the. reactivtles of clusters,The structure and principle of the apparatus were presented,By the apparatus the reactions between silver and sulfur clusters were studied. The experments indi- cate that the products from the reactions Between silver and sulfur clusters mainly include and In comparison to the experimental results from Fourier Transform lon Cyclotron Resonance (FTICR) spectrometer, it shows that the new apparatrus is very efficient for study on reactions between clusters.

关 键 词：团簇反应 激光串级溅射 银 硫 FTICR 

分 类 号：O614.122[理学—无机化学] O644.18[理学—化学]