邻苯二胺及其金属配位型含氟聚酰胺磺酰胺的合成与荧光性能  

Synthesis and Fluorescent Properties of o-Phenylenediamine and Its Metal Coordination-Complexes Based Fluoropoly(amide-sulfonamide)s

作　　者：文晓文[1] 陈欢[1] 李虹[1] 张永明[1] 

机构地区：[1]上海交通大学化学化工学院,上海200240

出　　处：《功能高分子学报》2010年第1期1-6,共6页Journal of Functional Polymers

基　　金：国家自然科学基金(20504020);国家"十一五"科技支撑计划重大项目(2006BAE02A00);国家863项目(2006AA03Z216)

摘　　要：采用溶解聚合法使β-四氟乙烷磺内酯分别与邻苯二胺、二氯-邻苯二胺合锌(Ⅱ)和二氯-邻苯二胺合镉(Ⅱ)开环缩聚,制备出邻苯二胺型和金属配位邻苯二胺型含氟聚酰胺磺酰胺聚合物。通过红外光谱、核磁共振氢谱、电感耦合等离子体发射光谱仪、凝胶渗透色谱等手段,确定其分子链为同时含有酰胺、磺酰胺、氟碳基团、芳环和金属离子的特殊结构;采用紫外-可见分光光度计和荧光分光光度计分析表明:邻苯二胺型含氟聚酰胺磺酰胺具有高荧光量子产率0.65,Cd2+配位后荧光量子产率保持0.65,而络合Zn2+的邻苯二胺型含氟聚酰胺磺酰胺的荧光量子产率降低为0.39,Zn2+对该类聚合物的荧光性能具有选择性。Novel fluorine-containing polymers,o-phenylenediamine and its metal coordination-complexes based fluoropoly（amide-sulfonamide）s were synthesized for the first time by solution polycondensation of β-hydroxytetrafluoroethanesulfonic acid sultone（TFE-sultone） and o-phenylenediamine,Zn（o-PDA）Cl_2 and Cd（o-PDA）Cl_2.Chemical structures of the obtained F-PASAs were characterized by GPC,FT-IR,~1H-NMR and ICP-AES in detail.Fluorescence quantum yields were investigated by UV-Vis and Fluorospectrophotometer.Results show that these functionalized fluoropolymers possess distinctive structures as well as unique fluorescent properties.o-Phenylenediamine based fluoropoly（amide-sulfonamide）s show a high fluorescence quantum yield of 0.65,and Cd（oPDA）Cl_2 based fluoropoly（amide-sulfonamide）s display the same fluorescence quantum yield,while fluorescence quantum yield of Zn（o-PDA）Cl_2 based ones are（decreased） to 0.39,which indicate the negative influence of Zn^（2＋） on fluorescence quantum yield.

关 键 词：邻苯二胺型含氟聚酰胺磺酰胺 金属离子配位聚合物 溶液缩聚 荧光量子产率 

分 类 号：O631[理学—高分子化学]