2,4-二氧代-1,3,2-苯并二氮磷杂环己烷与■C=C■及CS_2加成反应的研究  

Addition Reaction of l,3,2-Benzodiazaphosphorin-4(1H)-one 2 Oxides with Alkene

作　　者：陈茹玉[1] 包容[1] 

机构地区：[1]南开大学元素有机化学研究所

出　　处：《高等学校化学学报》1989年第12期1197-1201,共5页Chemical Journal of Chinese Universities

基　　金：国家自然科学基金

摘　　要：本文研究了2,4-二氧代-1,3,2-苯并二氮磷杂环己烷的磷氢键对β-硝基苯乙烯、丙烯酸酯、丙烯腈及二硫化碳的加成反应,共合成了18个新的加成产物.发现通过选用不同的碱或控制碱的用量.可选择性的进行加成或开环反应.由X衍射证实:在加成产物的结构中,环外P-C键构象因受磷杂环船式构象影响,以邻位交叉式(A)为主.The addition reaction of 1, 3,2-benzodiazaphosphorin-4(1H)-one 2 oxides with has been studied. The structures of the eighteen new compounds synthesized have been confirmed by elemental analysis, IR, 1H NMR and MS. The condition of the reaction and conformation of P-C of products were discussed. It was found that when the mol ratio of sodium ethoide/ I was 1: 1, the ring of compound I would open and when the mol ratio was 1:5, the addition reaction with would take place. But, if sodium hydride of equal mol ratio to I was used as the catalyst, the addition reaction of compound I with would take place exclusively.

关 键 词：有机磷化合物 除草剂 加成 开环 

分 类 号：O627.51[理学—有机化学]