8-羟基喹啉铱(Ⅲ)配合物的合成及其光学性质  

Synthesis and Optical Property of Iridium(Ⅲ) Complexes with 8-Hydroxyquinoline

作　　者：何彦波[1] 易春[1] 曹迁永[1] 邓阳生[1] 高希存[1] 

机构地区：[1]南昌大学理学院化学系,江西南昌330031

出　　处：《合成化学》2010年第2期235-238,共4页Chinese Journal of Synthetic Chemistry

基　　金：国家自然科学基金资助项目(60868001)

摘　　要：以2-苯基吡啶为原料,经两步反应合成了3个8-羟基喹啉衍生物铱(Ⅲ)配合物(2a^2 c),并研究和比较了2的光学性质和电化学行为。Three Iridium （ Ⅲ ） complexes with the ligands of 5-chloro and 2-methyl substituted 8- hydroxyquinoline and 2-phenylpyridine were synthesized by a two-step reaction from 2-phenylpyridine. The structures were characterized by 1^ H NMR and element analysis. Their UV-Vis absorption, fluorescence emission and electrochemical behaviors were studied and compared.

关 键 词：2-苯基吡啶 铱(Ⅲ)配合物 8-羟基喹啉衍生物 合成 光学性质 

分 类 号：O614.82[理学—无机化学] O626.32[理学—化学]