基于静态呼吸图技术的图案化方法  

A Novel Path to Patterning Based on the Static Breath Figure Technique

作　　者：李磊[1] 钟雅文[1] 陈财康[1] 李剑[1] 

机构地区：[1]厦门大学材料学院,福建厦门361005

出　　处：《物理化学学报》2010年第4期1135-1142,共8页Acta Physico-Chimica Sinica

基　　金：国家自然科学基金(50703032;20974089);福建省杰出青年基金(2009J06029);教育部新世纪人才基金项目资助~~

摘　　要：对呼吸图技术制备二维有序多孔结构的研究进展进行了综合评述,并重点介绍了本课题组发展的静态呼吸图技术.利用静态呼吸图法,可制备高度有序的聚合物、聚合物/无机物微孔膜.这些有序的结构可以直接应用于光掩膜.进一步,多孔聚合物膜可以被紫外光交联和改性.表面改性的多孔聚合物膜可以用于细胞支架.而交联的聚合物/无机物前驱体微孔膜可以用来制备无机纳米材料阵列.结果表明,静态呼吸图技术是一种简单、高效的对聚合物、聚合物/无机物薄膜进行图案化的通用方法,并展示了图案化薄膜广阔的功能化前景.The breath figure technique is one of the most promising strategies for the fabrication of large-sized patterns containing an ordered two-dimensional array of holes.In this review,particular emphasis is placed on the static breath figure technique,which is a robust methodology suitable for various polymers including linear polystyrene （PS）,amphiphilic diblock copolymers and polymer/inorganic precursor hybrid films.The resultant highly ordered microporous polymer films can be used as a mask for lithography.Moreover,the microporous polymer films can be surface modified and cross-linked by UV irradiation.The surface modified films can potentially be applied as a cell scaffold and the cross-linked polymer/hybrid films can be used as templates for the growth of nanomaterial arrays.

关 键 词：静态呼吸图 嵌段聚合物 图案化 

分 类 号：O631.3[理学—高分子化学]