羟胺法合成羟肟酸类捕收剂的研究进展  

Advances in synthesis of hydroxamic acid collectors from hydroxylamine

作　　者：张宝元[1] 钟宏[1] 

机构地区：[1]中南大学化学化工学院,湖南长沙410083

出　　处：《现代化工》2010年第4期11-15,共5页Modern Chemical Industry

摘　　要：对羟肟酸类捕收剂的浮选机理、羟胺法合成羟肟酸的原理和方法进行了介绍和分类;在考察醇、醇/水、水溶液和乳液4种肟化反应介质下工艺特点的同时,详细阐述了羟胺法改进工艺的研究进展;针对羟胺法的工艺特点和羟肟酸分子构效关系,提出了羟胺法合成羟肟酸的发展趋势。The mechanisms of hydroxamic acid as collectors on flotation, hydroxylamine method for synthesis of hydroxamic acid, and synthetic methods are brifely introduced and sorted. The development of hydroxylamine method, including four reaction mediums such as alcohols, alcohols/water, aqueous and emulsion are reviewed. Based on the process of hydroxylamine method and structure-activity relationship （ SAR ） of hydroxamic acid, some prospects of hydroxamic acid collectors synthesized by hydroxylamine method are pointed out.

关 键 词：捕收剂 羟胺法 羟肟酸 合成 

分 类 号：O622.5[理学—有机化学]