含氰基侧基聚芳醚砜的合成与表征  

Synthesis and Characterization of Poly(arylene ether sulfone)s with Cyano Pendant Group

作　　者：唐安斌[1] 蒋启泰[1] 朱蓉琪[1] 周宗孝 蔡兴贤[1] 

机构地区：[1]四川联合大学高分子材料系

出　　处：《合成化学》1998年第4期376-382,共7页Chinese Journal of Synthetic Chemistry

基　　金：国家自然科学基金

摘　　要：以２，６－二卤苯甲腈、４，４′－二氯二苯砜、４，４′－二羟基二苯砜、间苯二酚、对苯二酚、酚酞及双酚Ａ为主要原料，合成了含不同结构单元和不同氰基含量的含氰基侧基的聚芳醚砜，并采用ＩＲ，１３ＣＮＭＲ等分析手段对其结构进行了表征。同时研究了结构单元和氰基含量对聚芳醚砜性能的影响。The Poly(arylene ether sulfone)s with different structural unit and cyano content were synthesized from 2,6 dihalogenbenzonitrile, 4,4′ dichlorodiphenyls ulphone, 4,4′ dihydroxydiphenylsul fone, resorcinol, hydroquinone and 2,2 bis(p hydroxyphenyl) propane. The structure of the polymer was characterized by IR and 13 C NMR. The effects of structural unit and cyano content on the properties of poly(arylene ether sulfone)s were also discussed.

关 键 词：聚芳醚砜 氰基侧基 结构 PENS 聚芳醚腈砜 

分 类 号：O633[理学—高分子化学]