二氯二茂锆取代芳肟的合成与结构  

Synthesis and Sturcture of Mono substituted Aromatic Oximates of Zirconocene Dichloride

作　　者：于彤[1,2] 张玉鸿[1,2] 王俊杰[1,2] 

机构地区：[1]中山学院应用化学系 [2]内蒙古大学化学系

出　　处：《合成化学》1998年第4期393-397,共5页Chinese Journal of Synthetic Chemistry

摘　　要：二氯二茂锆与等当量的各种芳肟的钠盐在二氯甲烷中反应，得到１０种二氯二茂锆取代衍生物，均为新化合物。这些化合物对水、空气和光敏感，稳定性差。对它们的合成及ＩＲ，１ＨＮＭＲ进行了初步讨论。Ten new mono substituted aromatic oximates of zirconocene dichloride have been prepared by reaction of Cp 2ZrCl 2 with sodium salts of aromatic oximates in dichloromethane. All of them are less stable and sensitive to water, air and light. The synthesis results and characteristics of IR and 1H NMR spectra of these compounds were preliminarly discussed.

关 键 词：二氯二茂锆 芳肟 合成 衍生物 

分 类 号：O625.44[理学—有机化学] O627.43[理学—化学]