聚氨乙基甲基丙烯酸酯接枝丝氨酸的绿色合成  

Green Synthesis of Poly(Aminoethyl Methacrylate Hydrochloride)-g-Serine

作　　者：刘洋[1] 丁运生[1,2] 张涛[1] 

机构地区：[1]合肥工业大学化学工程学院高分子材料与化工研究所,安徽合肥230009 [2]可控化学与材料化工安徽省重点实验室,安徽合肥230009

出　　处：《广东化工》2010年第4期84-85,共2页Guangdong Chemical Industry

基　　金：安徽省年度重点科研项目(KJ2009A019);合肥工业大学创新实验项目(2009CXSY119;2009CXSY114)资助

摘　　要：文章将小分子丝氨酸接枝到聚氨乙基甲基丙烯酸酯盐酸盐的侧基,得到一种新型的水溶性功能高分子聚氨乙基甲基丙烯酸酯接枝丝氨酸(PAMA-g-Ser),经FTIR及1HNMR表征确定了各反应产物的结构。反应采用的原料低毒或无毒,各步反应条件温和、合成工艺简单、操作方便,产物分离提纯容易,实现了目标产物的绿色合成。Serine moieties was introduced to the pendant group of poly（aminoethyl methacrylate hydrochloride） and a novel water-soluble functional poly（aminoethyl methacrylate hydrochloride）-g-serine（PAMA-g-Ser） was obtained. The structures of compounds were confirmed by FTIR and IH NMR. The synthesis was developed by low or non-toxic materials, in mild reaction conditions, simpler synthetic method and convenient operations, meanwhile the compounds were easily to purify, so the ＂green＂ synthesis of PAMA-g-Ser has been realized.

关 键 词：氨乙基甲基丙烯酸酯盐酸盐 丝氨酸 绿色合成 

分 类 号：O632.52[理学—高分子化学]