Perfluorinated compounds in milk, milk powder and yoghurt purchased from markets in China  

作　　者：WANG JieMing SHI YaLi PAN YuanYuan CAI YaQi 

机构地区：[1]State Key Laboratory of Environmental Chemistry and Ecotoxicology Research Center for Eco-Environmental Sciences, Chinese Academy ofSciences, Beijing 100085, China

出　　处：《Chinese Science Bulletin》2010年第11期1020-1025,共6页

基　　金：supported by the Major Research Program of Chinese Academy of Sciences (Grant No. KZCX2-YW-420-1);National High-Technology Research and Development Program of China (Grant No. 2007AA06Z405);National Natural Science Foundation of China (Grant Nos. 20837003 and 20890111);the National Basic Research Program of China (Grant No.2009CB421605)

摘　　要：The exposure to perfluorinated compounds (PFCs) through the diet for humans is of great concern. Among the diet, dairy products are in great demand. This paper reports the study on the levels of 9 perfluorinated acids and 2 fluorotelomer acids in milk, milk powder and yoghurt purchased from Chinese markets from 2008 to 2009. The analytes were quantitated by high performance liquid chromatography/electrospray tandem mass spectrometry (HPLC-ESI-MS/MS). In milk samples, perfluoroheptanoic acid (PFHpA) and perfluorononanoic acid (PFNA) were detected frequently, both in 68% of samples. In milk powder samples, perfluorooctane sulfonate (PFOS), perfluorooctanoic acid (PFOA) and PFNA were the only detected PFCs and none of them was observed in more than 35% of samples. In yoghurt, PFOA was the most frequently detected compound, found in 69% of samples. None of fluorotelomer acids was observed in any samples. The mean concentrations of total PFCs were 178 pg/g (wet weight) in milk, 98 pg/g (dry weight) in milk powder and 42 pg/g in yoghurt (wet weight). It is notable that the data of this study indicate significant differences (P<0.001) among three kinds of packaging of milk in the concentration of total PFCs. A preliminary human health risk assessment of milk and dairy products consumption was conducted in this study. For adults, the mean daily intake of PFOS and total PFCs was equal to or lower than 23 and 167 pg kg-1 d-1 (body weight), respectively.The exposure to perfiuorinated compounds （PFCs） through the diet for humans is of great concern. Among the diet, dairy products are in great demand. This paper reports the study on the levels of 9 perfluorinated acids and 2 fluorotelomer acids in milk, milk powder and yoghurt purchased from Chinese markets from 2008 to 2009. The analytes were quantitated by high performance liquid chromatography/electrospray tandem mass spectrometry （HPLC-ESI-MS/MS）. In milk samples, perfluoroheptanoic acid （PFHpA） and perfiuorononanoic acid （PFNA） were detected frequently, both in 68% of samples. In milk powder samples, perfluorooctane sulfonate （PFOS）, perfluorooctanoic acid （PFOA） and PFNA were the only detected PFCs and none of them was observed in more than 35% of samples. In yoghurt, PFOA was the most frequently detected compound, found in 69% of samples. None of fluorotelomer acids was observed in any samples. The mean concentrations of total PFCs were 178 pg/g （wet weight） in milk, 98 pg/g （dry weight） in milk powder and 42 pg/g in yoghurt （wet weight）. It is notable that the data of this study indicate significant differences （P〈0.001） among three kinds of packaging of milk in the concentration of total PFCs. A preliminary human health risk assessment of milk and dairy products consumption was conducted in this study. For adults, the mean daily intake of PFOS and total PFCs was equal to or lower than 23 and 167 pg kg^-1 d^-1 （body weight）, respectively.

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