Crystal Structure of a Mn(Ⅱ) Coordination Polymer:[Mn(TP)(TBZH)_(2n)(TBZH=Thiabendazole,TP=Terephthalic Acid)  

作　　者：王家军 崔运成 刘力辉 黄艳菊 吕明 李传碧 高广刚 

机构地区：[1]Chemistry Department of Jilin Normal University

出　　处：《Chinese Journal of Structural Chemistry》2010年第2期240-244,共5页结构化学（英文）

基　　金：supported by Siping Sci-tech Development Planning Project (No 2005012)

摘　　要：The structure of a manganese（Ⅱ） polymer,[Mn（TP）（TBZH）]2n 1（TBZH=thiabendazole,TP=terephthalic acid）,has been determined by X-ray crystallography and characterized by elemental analysis,IR spectrum and thermogravimetric analysis.It crystallizes in the orthorhombic system,space group Pbcn with a=12.7813（12）,b=10.7544（10）,c=20.1270（19）A,V=2766.6（4）A^3,Z=8,C14H9Mn0.50N3O2S,Mr=310.77,Dc=1.492g/cm^3,F（000）=1268,μ=0.674 mm^-1 and S=1.064.The 1-D chain architecture of 1 is constructed from terephthalic acid and manganese atoms.Hydrogen bonds and aryl ring π-π stacking interactions in 1 contribute to form a 3-D supramo-lecular structure.The structure of a manganese（Ⅱ） polymer,[Mn（TP）（TBZH）]2n 1（TBZH=thiabendazole,TP=terephthalic acid）,has been determined by X-ray crystallography and characterized by elemental analysis,IR spectrum and thermogravimetric analysis.It crystallizes in the orthorhombic system,space group Pbcn with a=12.7813（12）,b=10.7544（10）,c=20.1270（19）A,V=2766.6（4）A^3,Z=8,C14H9Mn0.50N3O2S,Mr=310.77,Dc=1.492g/cm^3,F（000）=1268,μ=0.674 mm^-1 and S=1.064.The 1-D chain architecture of 1 is constructed from terephthalic acid and manganese atoms.Hydrogen bonds and aryl ring π-π stacking interactions in 1 contribute to form a 3-D supramo-lecular structure.

关 键 词：THIABENDAZOLE manganese（Ⅱ） complex single-crystal structure 

分 类 号：O631.3[理学—高分子化学]