Synthesis,Structure and Luminescence of a 1-D Chain of Copper(Ⅰ) Cyanide Decorated by Triphenylphosphine  

作　　者：秦莉 王飞 赵振国 张其胜 卢灿忠 

机构地区：[1]State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences

出　　处：《Chinese Journal of Structural Chemistry》2010年第2期270-274,共5页结构化学（英文）

基　　金：supported by the National Natural Science Foundation of China (20873150, 20821061, and 50772113);the Natural Science Foundation of Fujian Province (2007F3116, 2007HZ0001-1);the Chinese Academy of Sciences (KJCX2-YW-M05)

摘　　要：A new wave-like infinite chain coordination polymer [Cu3（CN）3（PPh3）4]n（1,PPh3=triphenylphosphine） has been synthesized by solution reaction and characterized by X-ray single-crystal structure diffraction analysis.The complex crystallizes in space group P1 with a=13.343（6）,b=13.429（7）,c=20.694（10）A,α=103.163（4）,β=96.704（5）,γ=101.981（6）o,V=3479（3）A^3,Z=2,C75H60Cu3N3P4,Mr=1317.76,Dc=1.258 g/cm^3,F（000）=1356,μ=1.043 mm^-1,the final R=0.0680 and wR=0.1305 for 9232 observed reflections with I〉2σ（I）.The infinite chain is linked by C-H…π H bonding interactions to form a 2-D supramolecular network.Luminescent study reveals that the complex has green-light emission.A new wave-like infinite chain coordination polymer [Cu3（CN）3（PPh3）4]n（1,PPh3=triphenylphosphine） has been synthesized by solution reaction and characterized by X-ray single-crystal structure diffraction analysis.The complex crystallizes in space group P1 with a=13.343（6）,b=13.429（7）,c=20.694（10）A,α=103.163（4）,β=96.704（5）,γ=101.981（6）o,V=3479（3）A^3,Z=2,C75H60Cu3N3P4,Mr=1317.76,Dc=1.258 g/cm^3,F（000）=1356,μ=1.043 mm^-1,the final R=0.0680 and wR=0.1305 for 9232 observed reflections with I〉2σ（I）.The infinite chain is linked by C-H…π H bonding interactions to form a 2-D supramolecular network.Luminescent study reveals that the complex has green-light emission.

关 键 词：copper（Ⅰ） cyanide C–H…π hydrogen bonds crystal structure LUMINESCENCE 

分 类 号：O627.51[理学—有机化学]