四磺化酞菁铝在水、醇-水、胶束体系中的二聚现象  

DIMERIZATION OF ALUMINUM PHTHALOCYANINESULFONATES IN WATER, AQUEOUS ALCOHOLIC SOLUTIONS AND MICELLES

作　　者：朱权[1,2] 吴星[1,2] 袁诗海 

机构地区：[1]扬州化工学校 [2]扬州大学师范学院化学化工系

出　　处：《扬州大学学报（自然科学版）》1998年第2期13-16,共4页Journal of Yangzhou University：Natural Science Edition

基　　金：江苏省教委自然科学基金

摘　　要：采用分光光度法研究了四磺化酞菁铝（ＡｌＴＳＰｃ）在水、醇（甲醇、乙醇、丙醇）水、胶束体系中的二聚行为，测定了配合物在上述体系中的二聚常数．结果表明：ＡｌＴＳＰｃ形成二聚体是一个慢反应，醇、胶束均可使二聚体发生解聚．The dimerization of aluminum(Ⅲ) tetrasulfonated phthalocyanine (AlTSPc) is studied in the water, aqueous alcoholic solution (MeOH, EtOH, PrOH), and micelles by spectraphotometic method. The dimerization constant K D is calculated from absorbance measurements. The results show that the dimerization reaction of AlTSPc is a slow reaction, the dimer of AlTSPc is dispersed by alcoholic and micelles.

关 键 词：四磺化酞菁铝 水 醇 铝配合物 二聚 胶束体系 

分 类 号：O614.31[理学—无机化学]