三维网状结构钴配合物的合成与晶体结构表征  

Synthesis and Cystal Stucture Characterization of Cobalt Complex with Three-dimensional Framework

作　　者：赵增兵[1,2] 台夕市[2] 

机构地区：[1]青海师范大学,青海西宁810008 [2]潍坊学院,山东潍坊261061

出　　处：《潍坊学院学报》2009年第6期84-86,共3页Journal of Weifang University

基　　金：国家自然科学基金(No.20671073);山东省自然科学基金(No.Y2007B60);潍坊市科技发展计划(2009)资助项目

摘　　要：以1,5-萘二磺酸钠为原料合成了一种钴的配合物,用X-单晶衍射仪测定其晶体结构。该配合物为单斜晶系,晶胞为P2(1)/c,晶胞参数:a=13.2216(18),b=6.67561(10),c=9.6957(15),β=92.0970(10),°V=855.2(2)3,Z=2,Mr=453.29,Dc=1.760 g/cm3,T=289(2)K,F(000)=466,μ(MoKa)=1.307 mm-1,R=0.0275,wR=0.0686,配合物分子通过分子内和分子间氢键形成三维网状结构。A cobalt complex was synthesized using 1,5-naphthalenedisufonic acid disodium salt as starting materials by solvent evaporation approach,and was determined the crystal structure by X-ray single crystal diffraction.The results showed that the compound was monoclinic,with P2（1）/c,a = 13.2216（18）,b = 6.6756（10）,c = 9.6957（15）,β = 92.0970（10） °,V = 855.2（2）3,Z = 2,M r= 453.29,Dc = 1.760 g/cm3,T = 289（2）K,F（000） = 466,μ（MoKa） = 1.307 cm-1,R = 0.0275 and Wr = 0.0686.The complex formed three-dimensional framework through intermolecular and intramolecular hydrogen bonds.

关 键 词：1 5-萘二磺酸钠 钴配合物 合成 晶体结构 

分 类 号：O641[理学—物理化学]