Synthesis and Crystal Structure of a Chiral Manganese(Ⅲ) Schiff Base Complex  

作　　者：陈东波 盛天录 王欣 陈建珊 胡胜民 傅瑞标 沈超君 邹青竹 吴新涛 

机构地区：[1]State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences [2]Graduate School of Chinese Academy of Sciences

出　　处：《Chinese Journal of Structural Chemistry》2010年第3期471-475,共5页结构化学（英文）

基　　金：Supported by the 973 Program (2007CB815301 and 2006CB932904);the National Natural Science Foundation of China (20333070, 20673118, 20871114);the Science Foundation of CAS (KJCX2-YW-M05);Fujian Province (2006J0014, 2006F3132)

摘　　要：A chiral salency complex,[Mn（Salency）（H2O）2]（PF6）·2H2O 1（Salency =（R,R）-N,N＇-bis（salicylidene）-1,2-cyclohexanediamine）,has been prepared by the reaction of Mn（CH3COO）3·2H2O with Salency and NH4PF6,and was established by X-ray diffraction techniques.The complex crystallizes in triclinic,space group P1 with a=9.299（8）,b=10.012（8）,c=13.461（11）,α=92.037（15）,β=92.974（12）,γ=93.530（18）°,V=1248.3（18）3,C20H28F6MnN2O6P,Mr = 592.35,Z=2,Dc=1.038 g/cm3,F（000）=608,μ=0.676 mm–1,the final R=0.0651 and wR=0.1880 for 5260 observed reflections with I 2σ（I）.A chiral salency complex,[Mn（Salency）（H2O）2]（PF6）·2H2O 1（Salency =（R,R）-N,N＇-bis（salicylidene）-1,2-cyclohexanediamine）,has been prepared by the reaction of Mn（CH3COO）3·2H2O with Salency and NH4PF6,and was established by X-ray diffraction techniques.The complex crystallizes in triclinic,space group P1 with a=9.299（8）,b=10.012（8）,c=13.461（11）,α=92.037（15）,β=92.974（12）,γ=93.530（18）°,V=1248.3（18）3,C20H28F6MnN2O6P,Mr = 592.35,Z=2,Dc=1.038 g/cm3,F（000）=608,μ=0.676 mm–1,the final R=0.0651 and wR=0.1880 for 5260 observed reflections with I 2σ（I）.

关 键 词：MANGANESE salency CHIRAL crystal structure π-π stacking 

分 类 号：O627.7[理学—有机化学]