HMCM-22/MCM-41的制备及其在甲苯碳酸二甲酯烷基化中的催化性能  

Synthesis of HMCM-22/MCM-41 and catalytic performance for toluene alkylation with dimethyl carbonate

作　　者：李永昕[1] 吴润泽[1] 薛冰[1] 

机构地区：[1]江苏工业学院化学化工学院,江苏常州213164

出　　处：《化工进展》2010年第5期875-879,共5页Chemical Industry and Engineering Progress

基　　金：江苏省高技术研究(BG2006015);江苏省高校重大基础研究(06KJA5013)资助项目

摘　　要：以自制的HMCM-22作为原料,与中孔分子筛MCM-41的凝胶在水热条件下进行组装得到HMCM-22/MCM-41中微孔复合分子筛,采用XRD、N2吸附-脱附及NH3-TPD等方法对合成样品进行表征。结果表明,合成的样品同时具有中孔分子筛MCM-41与微孔分子筛HMCM-22的特点。采用固定床微型连续流反应器对HMCM-22/MCM-41复合分子筛催化甲苯与碳酸二甲酯(DMC)的烷基化反应性能进行了评价,考察了反应温度、甲苯与DMC摩尔配比及空速对烷基化反应的影响。实验发现,HMCM-22/MCM-41催化甲苯DMC烷基化反应的产物中,对二甲苯的选择性远高于间位和邻位异构体的选择性,表现出良好的催化活性和选择性。HMCM-22/MCM-41 composite molecular sieves with mesoporous and microporous structure were prepared under hydrothermal conditions from HMCM-22.Physicochemical properties of the as-synthesized catalysts were characterized by XRD,N2 adsorption-desorption and NH3-TPD.Results showed the existence of well-structured microphase MCM-22 zeolite and mesophase MCM-41 in the composite materials.Selective alkylation of toluene with dimethyl carbonate （DMC） was carried out over HMCM-22/MCM-41 composite molecular sieves in a fixed-bed flow reactor.Effects of reaction conditions on the alkylation of toluene with DMC were investigated.The selectivity to p-xylene was higher than m- and o-isomers over HMCM-22/MCM-41 which exhibited good catalytic activity and selectivity.

关 键 词：HMCM-22/MCM-41复合分子筛 甲苯 碳酸二甲酯 对二甲苯 

分 类 号：TQ032.4[化学工程]