混凝-吸附处理黄河水及对氯消毒中氯衰减的影响  

Coagulation and Adsorption on Treating the Yellow River and the Impact on Chlorine Decay During Chlorination Process

作　　者：战晓[1] 高宝玉[1] 刘斌[1] 许春华[1] 岳钦艳[1] 

机构地区：[1]山东大学环境科学与工程学院,山东省水污染控制与资源化重点实验室,济南250100

出　　处：《环境科学》2010年第5期1198-1205,共8页Environmental Science

基　　金："十一五"国家科技支撑计划重点项目(2006BAJ06B05);"十一五"国家水污染控制与治理重大专项(2008ZX07422-003-02)

摘　　要：选用2种无机高分子混凝剂聚合氯化铁(PFC)和聚合氯化铝(PAC)处理黄河水,考察了混凝剂的投加量对浊度、UV254、DOC和高锰酸盐指数的去除效果,并结合混凝出水的Zeta电位分析其混凝机制.选择粉末活性炭与混凝联用,研究了混凝剂和吸附剂投加量以及二者的投加顺序对有机物去除效果的影响,并对混凝吸附后出水进行加氯消毒,考察水中残余氯随时间的变化.结果表明,2种混凝剂均有较高的浊度去除率(﹥90%).PAC对UV254、高锰酸盐指数和DOC的去除率分别为29.2%、26.1%和27.9%;PFC对三者的去除率分别为32.3%、23.3%和32.9%.PAC在混凝过程中,电中和作用占主导地位;PFC在混凝过程中,吸附架桥和电中和同时发挥作用.混凝-吸附联用处理黄河水样时,有机物的去除率随混凝剂和吸附剂投加量的增加而升高.先混凝后吸附工艺对UV254和DOC的去除效果优于先吸附后混凝工艺.先使用PAC混凝后吸附对UV254和DOC的去除率分别为95.2%和99.9%;对于PFC,先混凝后吸附对UV254和DOC的去除率分别为90.1%和99.9%.但是先投加粉末活性炭能提高矾花的沉降性能,且处理出水在保持持续消毒效果方面优于前者.Two types of inorganic polymer coagulants,polyferric chloride （PFC） and polyaluminum chloride （PAC）,were chosen to treat the Yellow River water. Different dosages were investigated in order to investigate the turbidity,UV254,DOC and permanganate index removal efficiency and their coagulation mechanisms based on the Zeta potentials. The natural organic matter removal by the combination of coagulation and adsorption with powder activated carbon were analyzed based on different coagulant and adsorbent dosages and dosing orders. The effects of combination of coagulation and adsorption on the residual chlorine decay were analyzed. The results showed that the two coagulants had high turbidity removal efficiency （ 〉90% ）. The UV254,DOC,permanganate index removal efficiency were 29. 2% ,26. 1% and 27. 9% respectively for PAC coagulation and were 32. 3% ,23. 3% and 32. 9% respectively for PFC. Electric neutralization played an important role in the PAC coagulation process while both adsorption bridging and electric neutralization performed when PFC was used. The removal percentage of organic matter increased with the increase coagulant and adsorbent. The adsorption after coagulation process gave the better UV254 and DOC removal efficiency than the coagulation after adsorption. The UV254 and DOC removal efficiency were 95. 2% and 99. 9% for PAC coagulation after adsorption and were 90. 1% and 99. 9% for PFC coagulation first. But adding powder activated carbon can improve floc settlement performance and maintained persistent disinfection effect.

关 键 词：混凝 吸附 黄河水 有机物 氯衰减 

分 类 号：X522[环境科学与工程—环境工程] TU991.2[建筑科学—市政工程]