FT-Raman拉曼光谱在金属有机化合物表征中的应用  

FT Raman Spectroscopic Characterization of Some Organometallic Compounds

作　　者：聂崇实[1] 

机构地区：[1]中国科学院上海有机化学研究所

出　　处：《光散射学报》1998年第3期145-150,共6页The Journal of Light Scattering

摘　　要：金属有机化学是化学研究中近半世纪来十分活跃和迅猛发展的领域，它作为新型有机合成试剂，均相催化剂和发展新材料在实际应用中已广为采纳。振动光谱是表征金属配合物和金属有机化合物的重要手段，已有不少好的总结文章［１］和专著［２］。回顾前人的工作，较多的利用红...Abstract FT Raman spectroscopy is proved to be a very powerful and convenient spectroscopic tool for organometallic compounds. The fluorescence and photodecomposition has been greatly reduced by using NIR laser excitation. Near fifty different kind of transition metal and extremely air sensitive lanthanide organometallic compounds with cyclopentadienyl, phenylcyclopentadienyl ligands as well as 3 oxa pentamethylenebridged bis(indenyl) ligand, were successfully measured and characterized by FT Raman.

关 键 词：金属有机化学 拉曼光谱 有机化合物表征 

分 类 号：O627[理学—有机化学] O657.37[理学—化学]