α(β)-四-苯氧基金属酞菁的合成、表征和光谱性质  

α(β)-tetra-phenoxy-metal phthalocyanine:synthesis,characteristics and spectrum properties

作　　者：白青龙[1,2] 张春花[2] 程传辉[1] 夏道成[1] 范昭奇[1] 杜国同[1] 

机构地区：[1]大连理工大学物理与光电工程学院三束材料改性国家重点实验室,大连116024 [2]内蒙古民族大学化学化工学院,通辽028043

出　　处：《化工新型材料》2010年第4期58-60,共3页New Chemical Materials

基　　金：国家自然科学基金(60807009)

摘　　要：以3-硝基邻苯二腈和4-硝基邻苯二腈为原料分别合成了1,8,15,22-四-苯氧基酞菁铜(镍)和2,9,16,23-四-苯氧基酞菁铜(镍),通过IR和UV-Vis光谱进行了表征,并讨论了取代基的取代位置和中心离子对酞菁Q带最大吸收波长的影响。We synthesized 1,8, 15, 22-tetra-phenoxy-copper （nickel） phthalocyanine, 1,8, 15, 22-tetra-phenoxy- nickel phthalocyanine, 2, 9, 16, 23-tetra-phenoxy-copper phthalocyanine and 2, 9, 16, 23-tetra-phenoxy-nickel phthalocyanine. The major precursors were 3-nitrobenzene-1, 2-dicarhonitrile and 4-nitrobenzene-I, 2-dicarbonitrile, respectively. They were characterized by elemental analysis, IR and UV-Vis, respectively. We also discussed the influence of the substitution position and the central metal ion on the maximum absorption wavelength of the phthalocyanine Q-band.

关 键 词：苯氧基金属酞菁 合成 表征 光谱性质 

分 类 号：O621.3[理学—有机化学]