若干5,10,15,20-四(4-羧基苯基)卟啉金属配合物的合成与表征  

Synthesis and Characterization of Some Metallic(Ⅱ) Complexes with meso-tetra(4-carboxyphenyl)porphyrin Ligand

作　　者：曾锦萍[1] 袁晓玲[1] 邓记华[1] 

机构地区：[1]宜春学院江西省高校应用化学与化学生物学重点实验室,江西宜春336000

出　　处：《宜春学院学报》2010年第4期14-17,共4页Journal of Yichun University

基　　金：江西省教育厅科技项目(GJJ08527;GJJ09356)

摘　　要：本文合成了四种5,10,15,20-四(4-羧基苯基)卟啉的过渡金属配合物。采用元素分析、电导测定、紫外-可见光谱、红外光谱、核磁共振和电喷雾质谱等多种物理手段表征了配合物的结构,对配合物的空间构型和成键性质进行了讨论。研究了配合物在氮气气氛中的热分解行为。结果表明:该类配合物中离域π键和螯合环的形成使M-N键加强,配合物很稳定。In this paper,four complexes containing ligand of meso-tetra（4-carboxyphenyl）porphyrin have been synthesized.Molecular structures of the synthesized compounds were confirmed by elemental analysis,conductivity measurement,UV-Vis spectra,IR spectra,1H NMR spectra and ESI-MS.The configuration and bonding character of complexes were discussed.Thermogravimetry（TG） for four compounds in an atmosphere of N2 were performed.In the chelating ring,conjugate π bonds were formed,which further strengthen the M-N coordination bonds and made complexes a stable compounds.

关 键 词：5 10 15 20-四(4-羧基苯基) 卟啉 配合物 表征 

分 类 号：O643.36[理学—物理化学]