壳寡糖希夫碱配合物的微波合成及结构表征  

Microwave Synthesis and Characterization of Chitooligosaccharides Schiff Base Complexes

作　　者：杨楠[1] 徐翠莲[2] 王彩霞[2] 樊素芳[2] 万峥凯[2] 赵铭钦[1] 

机构地区：[1]河南农业大学烟草学院国家烟草栽培生理生化研究基地,郑州市农业路63号450002 [2]河南农业大学理学院,郑州市农业路63号450002

出　　处：《光谱实验室》2010年第3期867-871,共5页Chinese Journal of Spectroscopy Laboratory

基　　金：国家烟草专卖局重大科技攻关项目(110200401004)

摘　　要：采用微波辐射加热法,以壳寡糖为原料,设计并合成了一系列壳寡糖希夫碱的金属配合物,其结构经紫外吸收、红外光谱、元素分析、ICP光谱和热重分析确认。该法具有反应时间短、温度条件易控、操作简便等特点,是一个值得推广的绿色合成方法。A series of chitooligosaccharides Schiff base complexes were synthesized from chitooligosaccharides under microwave irradiation and their structures were characterized by UV,IR,element analysis,ICP spectroscopy and TG.This method has advantages such as short time,easy operation and environmentally benign procedures compared with traditional method.

关 键 词：壳寡糖 希夫碱 微波合成 结构表征 

分 类 号：O657.61[理学—分析化学]