Hydrothermal Synthesis,Structure and Photo-luminescence of a 2D Lead（Ⅱ） Coordination Polymer with （4,6^3）Topology Based on Pb and 1,2,3,4-Butanetetracarboxylate Nodes  

作　　者：傅海萍 林景祥 胡海春 王玉玲 

机构地区：[1]College of Chemistry and Chemical Engineering,Jiangxi Normal University [2]Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences

出　　处：《Chinese Journal of Structural Chemistry》2010年第5期686-689,共4页结构化学（英文）

基　　金：Supported by the Education Department of Jiangxi Province (No. 2007-125);the Initial Fund for Doctors from Jiangxi Normal University

摘　　要：A lead（II） coordination polymer,{[Pb2（butca）（H2O）2]（H2O）2}n （1）,has been synthe-sized by the hydrothermal reaction of Pb（OH）2 and 1,2,3,4-butanetetracarboxylic acid （H4butca） at 160 °C.Single-crystal X-ray analyses reveal that it crystallizes in monoclinic,space group P21/c with a=7.616（5）,b=7.584（4）,c=12.314（7）,β=105.595（12）o,V=685.0（7）3,Z=4,C8H14O12Pb2,Mr=716.57,Dc=3.474 g/cm3,μ=24.610 mm-1,F（000）=644,the final R=0.0381 and wR=0.1176 for 1465 observed reflections with I 〉 2σ（I）.The complex presents a 2D-layered structure featuring two different types of rings,and has a （4,36）topology based on Pb and butca4-nodes.In solid state,complex 1 shows photoluminescence with the maximum emission intensity at 468 nm under 286 nm excitation.A lead（II） coordination polymer,{[Pb2（butca）（H2O）2]（H2O）2}n （1）,has been synthe-sized by the hydrothermal reaction of Pb（OH）2 and 1,2,3,4-butanetetracarboxylic acid （H4butca） at 160 °C.Single-crystal X-ray analyses reveal that it crystallizes in monoclinic,space group P21/c with a=7.616（5）,b=7.584（4）,c=12.314（7）,β=105.595（12）o,V=685.0（7）3,Z=4,C8H14O12Pb2,Mr=716.57,Dc=3.474 g/cm3,μ=24.610 mm-1,F（000）=644,the final R=0.0381 and wR=0.1176 for 1465 observed reflections with I 〉 2σ（I）.The complex presents a 2D-layered structure featuring two different types of rings,and has a （4,36）topology based on Pb and butca4-nodes.In solid state,complex 1 shows photoluminescence with the maximum emission intensity at 468 nm under 286 nm excitation.

关 键 词：lead（II） complex crystal structure （4 6^3 ）topology photoluminescence 

分 类 号：O631.3[理学—高分子化学]