新型一维钼氧链超分子化合物[(H_2bpe)Mo_4O_(13)]的合成与光学性质研究(英文)  

Hydrothermal Synthesis, Characterization and Luminescence Property of a New 1D Molybdenum Oxide Chain: [(H_2bpe)Mo_4O_(13)]

作　　者：吴晶晶[1] 韩占刚[1] 王彦娜[1] 郝青华[1] 翟学良[1] 

机构地区：[1]河北师范大学化学与材料科学学院,石家庄050016

出　　处：《无机化学学报》2010年第5期921-925,共5页Chinese Journal of Inorganic Chemistry

基　　金：国家自然科学基金(No.20701011);河北省教育厅自然科学基金基金(No.Z2006436);河北师范大学博士启动基金(No.L2005B13)资助项目

摘　　要：A new 1D compound [(H2bpe)Mo4O13] (1) (bpe=trans-1,2-Di-(4-pyridyl)-ethylen) was hydrothermally synthesized and characterized. Compound 1 comprises 3D supramolecular network constructed from 1D [Mo4O13]2-anion chains and protonated bpe layers via hydrogen bonds and π-π stacking interactions. The crystal data are the following: C12H12Mo4N2O13, Monoclinic, space group P21/n, a=0.968 64 (13) nm, b=1.349 68 (18) nm, c=1.514 9(2) nm, β=99.766(2)°, Z=4. The inorganic chain built up from only molybdenum oxide building blocks is interesting. The luminescent property of 1 was studied.A new 1D compound [（H2bpe）Mo4O13] （1） （bpe=trans-1,2-Di-（4-pyridyl）-ethylen） was hydrothermally synthesized and characterized. Compound 1 comprises 3D supramolecular network constructed from 1D [Mo4O13]2-anion chains and protonated bpe layers via hydrogen bonds and π-π stacking interactions. The crystal data are the following： C12H12Mo4N2O13, Monoclinic, space group P21/n, a=0.968 64 （13） nm, b=1.349 68 （18） nm, c=1.514 9（2） nm, β=99.766（2）°, Z=4. The inorganic chain built up from only molybdenum oxide building blocks is interesting. The luminescent property of 1 was studied.

关 键 词：钼氧链 晶体结构 光学性质 

分 类 号：O614.612[理学—无机化学]