银(Ⅰ)、锌(Ⅱ)与2,2′-(2-氨基-苯氧基)乙醚配合物的合成及晶体结构  

Synthesis and Crystal Structures of Ag(Ⅰ) and Zn(Ⅱ) Complexes Containing 2,2′-(2-amino-phenoxy)-ether Ligand

作　　者：朱兴城[1] 丁亚洲[1] 张奇龙[1] 朱必学[1] 

机构地区：[1]贵州大学,贵州省大环化学及超分子化学重点实验室,贵阳550025

出　　处：《无机化学学报》2010年第5期926-930,共5页Chinese Journal of Inorganic Chemistry

基　　金：国家自然科学基金项目(No.20861003);贵州省国际合作重点项目(No.黔科合外G字[2009]700104)资助

摘　　要：The compound 2,2′-(2-amino-phenoxy)-ether [L] was synthesized from the reaction of diethylene glycol with tosyl chloride. AgClO4 and ZnCl2 each react with L to give two complexes [Ag2L2(H2O)(ClO4)2] (1) and [ZnLCl2]n (2) respectively, and characterized by FTIR and single crystal X-ray diffraction. The results of structural analysis indicated that both complexes crystallize in the monoclinic system with space group P21/c. 1 is a dinuclear complex, and 2 forming 1D zigzag chain by Zn(Ⅱ) linking adjacent ligands in turn. When viewed from the top of the chain, the structure of 2 shows the unidimensional tube.The compound 2,2′-（2-amino-phenoxy）-ether [L] was synthesized from the reaction of diethylene glycol with tosyl chloride. AgClO4 and ZnCl2 each react with L to give two complexes [Ag2L2（H2O）（ClO4）2] （1） and [ZnLCl2]n （2） respectively, and characterized by FTIR and single crystal X-ray diffraction. The results of structural analysis indicated that both complexes crystallize in the monoclinic system with space group P21/c. 1 is a dinuclear complex, and 2 forming 1D zigzag chain by Zn（Ⅱ） linking adjacent ligands in turn. When viewed from the top of the chain, the structure of 2 shows the unidimensional tube.

关 键 词：2 2′-(2-氨基-苯氧基)乙醚 配合物 晶体结构 

分 类 号：O614.241[理学—无机化学] O614.122[理学—化学]