发展二氧化碳的绿色高新精细化工产业链促进产业结构优化节能减排  

Green chemical eco-industry for producing a series of fine chemical products using CO_2 instead of phosgene

作　　者：田恒水[1] 李峰[1] 陆文龙[1] 何国锋[1] 丁同梅[1] 赵贺猛[1] 王旭涛[1] 魏永梅[1] 朱云峰[1] 王贺玲[1] 

机构地区：[1]华东理工大学化工学院,上海200237

出　　处：《化工进展》2010年第6期977-983,共7页Chemical Industry and Engineering Progress

基　　金：国家自然科学基金(20376024);国家863计划(2006AA030204)资助项目

摘　　要：介绍了华东理工大学从烯烃生产环氧烷烃,二氧化碳合成碳酸二甲酯联产二元醇,以绿色化学原料碳酸二甲酯代替剧毒的光气,开发了碳酸甲乙酯、二乙酯、二丙酯、二丁酯、二苯酯、呋喃唑酮、碳酰肼、苯胺基甲酸甲酯、苄胺基甲酸甲酯、对苯二胺二甲酸甲酯、间羟苯胺基甲酸甲酯、间甲苯胺基甲酸甲酯、二胺基甲酸甲酯二苯甲烷、己二胺二甲酸甲酯、烷基胺甲酸甲酯、肼基甲酸甲酯、异氰酸酯、聚氨酯、聚碳酸酯、嘧黄隆、甲黄隆、氯黄隆等一系列绿色清洁生产新工艺。华东理工大学开发的新成果间接实现了二氧化碳替代剧毒的光气,形成了具有中国特色的二氧化碳的绿色高新精细化工产业链,可促进产业结构优化节能减排。The processes of dimethyl carbonate （DMC） production from carbon dioxide with co-production of diols and epoxide production from olefins are described. DMC,instead of toxic phosgene,is used to develop a series of new clean technologies for the production of fine chemicals,such as ethyl-methyl,diethyl,dipropyl and dibutyl carbonates,furazolidone,hydrazine carbonate,methyl phenylamine and benzylamine carbamates,dimethyl p-phenylenediamine dicarbamate,methyl m-hydroxyl-amine and m-toluidine carbamates,dimethyl 4,4＇-diphenyl methane and dimethyl-1,6-hexanediamine dicarbamates,alkylamine methyl carbamate,methyl hydrazine,isocyanate,PU,PC,sulfometuron,metsulfuron-methyl and chlorimuron-ethyl etc. These new production technologies with the use of carbon dioxide indirectly and with the replacement of toxic phosgene can promote the optimization of chemical industry structure and shape a green high-tech fine chemical eco-industry.

关 键 词：二氧化碳 羰基反应 清洁生产 替代光气 绿色化工产业链 

分 类 号：TQ26[化学工程—有机化工]