高效液相色谱法直接分离硒代缩水甘油醚对映异构体  

Enantioseparation of Glycidolselenide by High Performance Liquid Chromatography

作　　者：于兆文[1] 周志强[1] 蒋生祥[1] 陈立仁[1] 

机构地区：[1]中国科学院兰州化学物理研究所,兰州730000

出　　处：《分析化学》1999年第2期206-209,共4页Chinese Journal of Analytical Chemistry

基　　金：中国科学院重点基金资助项目

摘　　要：用高效液相色谱法在直链淀粉-三(苯基氨基甲酸酯)涂敷型手性固定相上直接拆分了7种新型外消旋硒代缩水甘油醚,考察了流动相组成、样品结构对保留和拆分的影响.Amy lose-tris(phenylcarbamate) coated on silica gel is a very useful chiral stationary phase. Seven racemic compounds of glycidolselenide were separated on the stationary phase by high performance liquid chromatography. The effect of 2-propanol concentration and the structure of the analytes on the retention and resolution were investigated.

关 键 词：对映体分离 固定相 硒代缩水甘油醚 拆分 HPLC 

分 类 号：O627.61[理学—有机化学]