β-环糊精聚合物玻璃SCOT柱的研制  

Preparation of a Capillary SCOT Column with Crosslinked β _ Cyclodextrin as the Stationary Phase

作　　者：罗春花 许鸿生[1,2] 田文荣 

机构地区：[1]衡阳师范高等专科学校 [2]湘潭大学化学化工学院

出　　处：《分析测试学报》1999年第1期61-63,共3页Journal of Instrumental Analysis

摘　　要：以环氧氯丙烷作交联剂合成了一种非水溶性的β－环糊精聚合物，用该聚合物作固定相研制成了柱效高、热稳定性好的玻璃ＳＣＯＴ柱，对丁醇异构体，二取代苯异构体，龙脑、异龙脑顺反异构体和旋光异构体进行了分离。A water _ insoluble β _ cyclodextrin polymer with epichlorohydrin as the crosslinking agent has been synthesized. The polymer was then employed as stationary phase of a highly effcient and thermally stable capillary SCOT column. Geometrical and optical isomers, such as butanol isomers, di _ substituted benzene isomer, borneol and isoborneol cis _ trans isomers, as well as some other antimers, can be satisfactorily separated on this column.

关 键 词：环糊精聚合物 玻璃SOCOT柱 固定相 色谱 

分 类 号：O657.703[理学—分析化学]