全(多)氟酰基过氧化物的化学及应用  

Per (poly )fluorodiacyl Peroxides - Chemistry and Application

作　　者：赵成学[1] 曲延玲[1] 贺海鹰 周志彬 

机构地区：[1]上海交通大学化学化工学院,上海200240

出　　处：《有机化学》1999年第1期15-26,共12页Chinese Journal of Organic Chemistry

摘　　要：综述了含氟新试剂全(多)氟酰基过氧化物的合成、热分解及其与富电子芳香族受物间的单电子转移反应的机理。并简要地介绍了它作为对芳环、芳杂环有效的全氟烷基化试剂及烯烃聚合的引发剂在合成含氟功能化合物领域中的重要应用。The synthesis of per (poly )fluorodiacyl peroxides, the kinetic studies and product analysis of their thermal decomposition, the mechanistic investigation of their electron - transfer reactions with electron -rich aromatics and nitrogen - containing substrates as well as their application as effective aromatic ring - per (poly)fluoro - alkylating agents and initiators of oligomerization of vinyl monomes are reviewed in this paper.

关 键 词：过氧化物 单电子转移 全氟酰基 多氟酰基 FAP 

分 类 号：O623.2[理学—有机化学]