水溶性高分子量聚苯乙烯磺酸钠的制备  

Preparation of the water-soluble high molecular weight poly(sodium styrenesulfonate)

作　　者：王喜超[1] 姜日善[1] 

机构地区：[1]延边大学化学系,吉林延吉133002

出　　处：《化学研究与应用》2010年第6期770-773,共4页Chemical Research and Application

摘　　要：The water-soluble high molecular weight Poly(sodium styrenesulfonate)(PSS) was prepared from polystyrene and sulfuric acid by suspension and azeotropic distilation methods,and its structure was characterized by chemical titration and 1H-NMR;Factors such as reactants ratio,temperature and time affecting the degree of sulfonation of polystyrene were investigated.The results indicated that the sulfonation degree was increased with an increase in the ratio(R) of sulfuric acid/polystyrene and reaction time.By azeotropic distilation method,PSS could be synthesized in the presence of equivalent amount of sulfuricThe water-soluble high molecular weight Poly（sodium styrenesulfonate）（PSS） was prepared from polystyrene and sulfuric acid by suspension and azeotropic distilation methods,and its structure was characterized by chemical titration and 1H-NMR;Factors such as reactants ratio,temperature and time affecting the degree of sulfonation of polystyrene were investigated.The results indicated that the sulfonation degree was increased with an increase in the ratio（R） of sulfuric acid/polystyrene and reaction time.By azeotropic distilation method,PSS could be synthesized in the presence of equivalent amount of sulfuric acid

关 键 词：聚苯乙烯 磺化 聚苯乙烯磺酸钠 

分 类 号：O632.13[理学—高分子化学]