以2,5-二巯基-1,3,4噻二唑(Ⅰ)为桥连配体的二维镉(Ⅱ)配合物的制备与晶体结构(英文)  

Preparation and Crystal Structure of a Two-Dimensional Cadmium(Ⅱ) Coordination Polymer Containing Bismuthiol(Ⅰ) as a Bridging Ligand

作　　者：王文祥[1] 赵红[1] 

机构地区：[1]东南大学化学化工学院有序物质科学研究中心,南京211189

出　　处：《无机化学学报》2010年第6期1109-1112,共4页Chinese Journal of Inorganic Chemistry

基　　金：国家自然科学基金(No.20801012);东南大学优秀青年教师项目(No.4007041027)资助

摘　　要：The hydrothermal reaction of CdCl2with 1,3,4-thiadiazole-2,5-dithiol affords one 2D network cadmium(Ⅱ) coordination polymer, [Cd(5-thioxo-4,5-dihydro-1,3,4-thiadiazole-2-thiolate)2]n. The structure was determined by single crystal X-ray diffraction, the crystal belongs to orthorhombic system with space group Pbcn, and a=1.281 6(2) nm, b=1.162 1(2) nm, c=0.784 06(16) nm, V=1.167 7(4) nm3, Z=4. Its fluorescence was measured. CCDC: 689817.The hydrothermal reaction of CdCl2with 1,3,4-thiadiazole-2,5-dithiol affords one 2D network cadmium（Ⅱ） coordination polymer, [Cd（5-thioxo-4,5-dihydro-1,3,4-thiadiazole-2-thiolate）2]n. The structure was determined by single crystal X-ray diffraction, the crystal belongs to orthorhombic system with space group Pbcn, and a=1.281 6（2） nm, b=1.162 1（2） nm, c=0.784 06（16） nm, V=1.167 7（4） nm3, Z=4. Its fluorescence was measured. CCDC： 689817.

关 键 词：镉配合物 水热合成 晶体结构 荧光性质 

分 类 号：O614.242[理学—无机化学]