γ-氨丙基杂氮硅三环酰胺类衍生物的合成及其植物生长调节活性研究  

Synthesis of γ-aminopropyl silatrane derivatives and research on its plant growth-regulating activity

作　　者：胡素文[1] 张庆伟[1] 宋博[1] 叶发青[1] 郭平[1] 刘剑敏[1] 韩安月[1] 叶云[1] 

机构地区：[1]温州医学院药学院,浙江温州325035

出　　处：《温州医学院学报》2010年第3期221-223,共3页Journal of Wenzhou Medical College

基　　金：浙江省自然科学基金资助项目(Y204087)

摘　　要：目的:合成3个目标化合物,并测试其对单子叶植物玉米、双子叶植物萝卜的生长调节作用。方法:以三异丙醇胺和γ-氨丙基三乙氧基硅烷为原料,通过硅烷化、酰化反应合成目标化合物。将目标化合物分别用蒸馏水配制成浓度为2O、5O和100 ppm的溶液,采用平皿法测试目标化合物对单子叶植物玉米和双子叶植物萝卜的生长调节作用。结果:合成目标化合物;且结构经IR、MS、1H-NMR及元素分析确证;目标化合物在3个浓度下对单子叶植物玉米和双子叶植物萝都表现出一定的生长调节活性,在50 ppm时促进生长作用较为明显。结论:目标化合物对玉米种子和萝卜种子有一定的生长调节作用。Objective：To synthesize three target compounds in order to explore the growth regulating activity on radishes and corns.Methods：Triisopropanolamine and γ-aminopropyltriethoxysilane were used as raw materials to obtain the new target compounds through silylation and acylation.Method of plating test was used to examine growth regulating activity of target compounds on radishes of amphibrya and corns of dicotyledon under the concentration of 20,50,100 ppm.Results：The stucture of target compounds were identified by 1H-NMR,MS,IR and elemental analysis.The test results showed that all compounds have definite plant growth regulating activity.The optimal concentration of target compounds for promoting plant growth was 50 ppm.Conclusion：The target compounds have definite growth regulating function for the radish seeds and corn seeds.

关 键 词：杂氮硅三环 化学合成 植物生长调节活性 

分 类 号：O621.29[理学—有机化学]