龟裂树脂乳液共聚反应动力学研究  

Study on Polymerization Dynamics of CSA Cracking Resin Emulsion

作　　者：柴淑玲[1] 

机构地区：[1]山东轻工业学院轻化工系

出　　处：《皮革化工》1999年第2期1-2,7,共3页Leather Chemicals

摘　　要：采用乳液共聚法制备ＣＳＡ型龟裂树脂乳液，主要讨论了乳化剂用量、引发剂用量、反应温度对单体转化率和乳液性能的影响规律，并计算出温度对初期聚合反应速率影响的表观活化能是１０７．８８ｋＪ／ｍｏｌ。The CSA cracking resin emulsion has been prepared by emulsion copolymerization. The influence of the amounts of emulsifier and initiator, and the polymerization temperature on the transform ratio of monomer and the emulsion properties has been discussed in this paper. It has been calculated that the apparent activation energy of influence on stage polymerization ratio in the early about temperature is 107.88 kJ/mol.

关 键 词：龟裂树脂 动力学 聚合 乳液共聚 CSA型 

分 类 号：O631.5[理学—高分子化学]